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Abstract The South Atlantic Convergence Zone (SACZ) is an atmospheric system occurring in austral summer on the South America continent and sometimes extending over the adjacent South Atlantic. It is characterized by a persistent and very large, northwest-southeast-oriented, cloud band. Its presence over the ocean causes sea surface cooling that some past studies indicated as being produced by a decrease of incoming solar heat flux induced by the extensive cloud cover. Here we investigate ocean–atmosphere interaction processes in the Southwestern Atlantic Ocean (SWA) during SACZ oceanic episodes, as well as the resulting modulations occurring in the oceanic mixed layer and their possible feedbacks on the marine atmospheric boundary layer. Our main interests and novel results are on verifying how the oceanic SACZ acts on dynamic and thermodynamic mechanisms and contributes to the sea surface thermal balance in that region. In our oceanic SACZ episodes simulations we confirm an ocean surface cooling. Model results indicate that surface atmospheric circulation and the presence of an extensive cloud cover band over the SWA promote sea surface cooling via a combined effect of dynamic and thermodynamic mechanisms, which are of the same order of magnitude. The sea surface temperature (SST) decreases in regions underneath oceanic SACZ positions, near Southeast Brazilian coast, in the South Brazil Bight (SBB) and offshore. This cooling is the result of a complex combination of factors caused by the decrease of solar shortwave radiation reaching the sea surface and the reduction of horizontal heat advection in the Brazil Current (BC) region. The weakened southward BC and adjacent offshore region heat advection seems to be associated with the surface atmospheric circulation caused by oceanic SACZ episodes, which rotate the surface wind and strengthen cyclonic oceanic mesoscale eddy. Another singular feature found in this study is the presence of an atmospheric cyclonic vortex Southwest of the SACZ (CVSS), both at the surface and aloft at 850 hPa near 24°S and 45°W. The CVSS induces an SST decrease southwestward from the SACZ position by inducing divergent Ekman transport and consequent offshore upwelling. This shows that the dynamical effects of atmospheric surface circulation associated with the oceanic SACZ are not restricted only to the region underneath the cloud band, but that they extend southwestward where the CVSS presence supports the oceanic SACZ convective activity and concomitantly modifies the ocean dynamics. Therefore, the changes produced in the oceanic dynamics by these SACZ events may be important to many areas of scientific and applied climate research. For example, episodes of oceanic SACZ may influence the pathways of pollutants as well as fish larvae dispersion in the region. 

Abstract Sea surface temperature (SST) anomalies caused by a warm core eddy (WCE) in the Southwestern Atlantic Ocean (SWA) rendered a crucial influence on modifying the marine atmospheric boundary layer (MABL). During the first cruise to support the Antarctic Modeling and Observation System (ATMOS) project, a WCE that was shed from the Brazil Current was sampled. Apart from traditional meteorological measurements, we used the Eddy Covariance method to directly measure the ocean–atmosphere sensible heat, latent heat, momentum, and carbon dioxide (CO₂) fluxes. The mechanisms of pressure adjustment and vertical mixing that can make the MABL unstable were both identified. The WCE also acted to increase the surface winds and heat fluxes from the ocean to the atmosphere. Oceanic regions at middle and high latitudes are expected to absorb atmospheric CO₂, and are thereby considered as sinks, due to their cold waters. Instead, the presence of this WCE in midlatitudes, surrounded by predominantly cold waters, caused the ocean to locally act as a CO₂source. The contribution to the atmosphere was estimated as 0.3 ± 0.04 mmol m⁻²day⁻¹, averaged over the sampling period. The CO₂transfer velocity coefficient (K) was determined using a quadratic fit and showed an adequate representation of ocean–atmosphere fluxes. The ocean–atmosphere CO₂, momentum, and heat fluxes were each closely correlated with the SST. The increase of SST inside the WCE clearly resulted in larger magnitudes of all of the ocean–atmosphere fluxes studied here. This study adds to our understanding of how oceanic mesoscale structures, such as this WCE, affect the overlying atmosphere.